Aquarium filters are critical components of both freshwater and marine aquaria.Leibel WS (1993) A fishkeepers guide to South American cichlids. Tetra Press. Belgium pg 12-14. Aquarium filters remove physical and soluble chemical waste products from aquaria, simplifying maintenance. Furthermore, aquarium filters are necessary to support life as aquaria are relatively small, closed volumes of water compared to the natural environment of most fish.Sands D (1994) A fishkeepers guide to Central American cichlids. Tetra Press. Belgium pg 17-19.
Overview Animals, typically fish, kept in fish tanks produce waste from excrement and respiration. Another source of waste is uneaten food or plants and fish which have died. These waste products collect in the tanks and contaminate the water. As the degree of contamination rises, the risk to the health of the aquaria increases and removal of the contamination becomes critical. Filtration is a common method used for maintenance of healthy aquaria.
Biological filtration and the nitrogen cycle
Proper management of the nitrogen cycle is a vital element of a successful aquarium. Excretia and other decomposing organic matter produce ammonia which is highly toxic to fish. Bacterial processes oxidize this ammonia into the slightly less toxic nitrites, and these are in turn oxidized to form the much less toxic nitrates. In the natural environment these nitrates are subsequently taken up by plants as fertilizer and this does indeed happen to some extent in an aquarium planted with real plants.
An aquarium is, however, an imperfect microcosm of the natural world. Aquariums are usually much more densely stocked with fish than the natural environment. This increases the amount of ammonia produced in the relatively small volume of the aquarium. The bacteria responsible for breaking down the ammonia by converting it to nitrite, Nitrosomonas, colonize the surface of any objects inside the aquarium. The bacteria that then convert nitrite to nitrate are Nitrospira and Nitrobacter. In most cases, a biological filter is nothing more than a chemically inert porous sponge, which provides a greatly enlarged surface area on which these bacteria can develop. These bacterial colonies take several weeks to form, during which time the aquarium is vulnerable to a condition commonly known as "new tank syndrome" if stocked with fish too quickly. Some systems incorporate bacteria capable of converting nitrates into nitrogen gas.
Accumulation of toxic ammonia from decomposing wastes is the largest cause of fish mortality in new, poorly maintained, or overloaded aquariums. In the artificial environment of the aquarium, the nitrogen cycle effectively ends with the production of nitrates. In order that the nitrate level does not build up to a harmful level regular partial water changes are required to remove the nitrates and introduce new, uncontaminated water.
Mechanical and chemical filtration The process of mechanical filtration removes particulate material from the water column. This particulate matter may include uneaten food, feces or plant or algal debris. Mechanical filtration is typically achieved by passing water through materials which act as a sieve, physically trapping the particulate matter. Removal of solid waste can be as simple as physical hand netting of debris, and/or involve highly complex equipment. All removal of solid wastes involve filtering water through some form of mesh in a process known as mechanical filtration. The solid wastes are first collected, and then must be physically removed from the aquarium system. Mechanical filtration is ultimately ineffective if the solid wastes are not removed from the filter, and are allowed to decay and dissolve in the water.
Dissolved wastes are more difficult to remove from the water. Several techniques, collectively known as chemical filtration, are used for the removal of dissolved wastes, the most popular being the use of activated carbon and foam fractionation. To a certain extent, healthy plants extract dissolved chemical wastes from water when they grow, so plants can serve a role in the containment of dissolved wastes.
A final and less common situation requiring filtration involves the desire to sterilize water-borne pathogens. This sterilization is accomplished by passing aquarium water through filtration devices which expose the water to high intensity ultraviolet light and/or exposing the water to dissolved ozone gas.
Materials suitable for aquarium filtration
Numerous materials are suitable as aquarium filtration media. These include synthetic wools, known in the aquarium hobby as filter wool, made of polyethylene terephthalate or nylon. Synthetic sponges or foams, various ceramic and sintered glass and silicon products along with igneous gravels are also used as mechanical filter materials. Materials with a greater surface area provide both mechanical and biological filtration. Some filter materials, such as plastic "bioballs", are best used for biological filtration.
With the notable exception of diatom filters, aquarium filters are rarely purely mechanical in action, as bacteria will colonise most filter materials effecting some degree of biological filtration. Activated carbon and zeolites are also frequently added to aquarium filters. These highly porous materials act as adsorbates binding various chemicals to their large external surfaces and also as sites of bacterial colonisation.
The simplest type of aquarium filter consists only of filter wool and activated carbon. The filter wool traps large debris and particles, and the activated carbon adsorbs smaller impurities. These should be changed regularly at suitable intervals. This is particularly important in the case of activated carbon filters, which may re-release their adsorbed contents in large (and therefore harmful) doses if they are allowed to saturate. Activated carbon adsorbs toxins on the extended porous surface of the carbon. It cannot be reactivated by boiling in water. The adsorption of activated carbon can be restored by thermal regeneration at temperatures of , electrochemical regeneration, ultrasound, or other industrial processes. For the aquarist, replacing the activated carbon with fresh material is simple and inexpensive.
Types
Numerous types of aquarium filters are commercially available, including:
Power filters Power or HOB (hang on back) filters, which are impeller powered, remove water from the aquarium, usually with a long siphoning tube, which is then pushed (or pulled) through a series of different filter media and returned to the aquarium. These are the most common type of aquarium filter. They are often more suitable for larger tanks than other types. However, they are not necessarily the best for smaller tanks, since they have a tendency to cause an excess of water flow in smaller tanks. Other types, such as sponge filters, are ideal in this environment.
Advantages of this type of filter are that they allow for a selection of different types of filter media depending on the tank needs, and that they are easy to clean without disturbing the inhabitants of the tank because they sit on the outside of the fish tank. Disadvantages of power filters include their smaller capacity for filter media compared to canister filters, their aforementioned tendency to create excessive flow rates, and that they tend to be very noisy, usually resulting from vibrations.
Canister filters Compared to filters that hang on the back of the aquarium, canister-style external filters offer a greater quantity of filter materials to be used along with a greater degree of flexibility with respect to filter material choice. Water enters the canister filled with the chosen filter material through an intake pipe at the bottom of the canister, passes through the material, and is fed back to the aquarium through the return pipe. Water is forced to circulate through the filter by a pump typically installed at the top of the canister.
Canister filters are sealed, fully flooded systems, meaning that the aquarium, intake pipe, filter interior and the return pipe form a continuous body of water. In this configuration both the intake and return path form two siphons, which precisely counterbalance each other. Under these circumstances, the filter pump does not have to spend any effort to lift the water back to the aquarium, regardless of how high the latter is installed above the canister. The pump should only be powerful enough to push the water through the filtering material as well as overcome the drag in the intake and return pipes. This makes canister filter pumps virtually insensitive to the height difference between the aquarium and the filter (although exceeding the manufacturer-specified height limit can lead to leaks).
Benefits of this type of filter are that they can provide a high volume of filter material without reducing the internal space in the aquarium, and that they can be disconnected from the tank for cleaning/maintenance and replaced without disturbing the aquarium interior or occupants. Also, as a filter with external plumbing, it supports in-line installation of other aquarium equipment, such as water heaters and carbon dioxide diffusers. Such equipment can be removed from the tank and installed in-line into the return pipe of the filter. Disadvantages of canister filters include the increased cost and complexity relative to internal filters and difficulties in cleaning the tubes which transfer water to and from the aquarium. There is also the risk of a leak, which naturally is an issue for any filter placed outside of the aquarium. They, too, fall victim to the issue of excess water flow.Benefits of using a Canister Filter
Canister filters were initially designed to filter drinking water, under low pressure. Canister filters for aquariums use high water pressure, from a properly powered pump, to force water through the dense filter media. A pump can draw water from an under-gravel filter, and run it into a canister for double filtration.
Diatom filters Diatom filters are used only for sporadic cleaning of tanks, they are not continuously operated on aquariums. These filters utilise diatomaceous earth to create an extremely fine filter down to 1 μm which removes particulate matter from the water column.
Trickle filters
Trickle filters, also known as wet/dry filters are another water filtration systems for marine and freshwater aquariums. This filter comes in two configurations, one which is placed on top of the aquarium (more rarely seen) and one which is placed below the aquarium (more common).
If the wet/dry filter is placed on top of the aquarium, water is pumped over a number of perforated trays containing filter wool or some other filter material. The water trickles through the trays, keeping the filter wool wet but not completely submerged, allowing aerobic bacteria to grow and aiding biological filtration. The water returns to the aquarium like rain.