Dejmek (feminine: Dejmková) is a Czech surname. It was derived from the Czech word dým ('smoke') and there is a theory that it may have originated as a nickname for a curly-haired person. A similar surname with the same origin is Dejmal. Notable people with the surname include:

Kazimierz Dejmek (1924–2002), Polish actor, theatre and film director, and politician Natálie Dejmková (born 1996), Czech ski jumper Radek Dejmek (born 1988), Czech footballer

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