Valuev or Valuyev () is a Russian surname. Notable people with the surname include:
Grigory Valuyev (? - after 1623), Russian voyevoda Nikolai Valuev (born 1973), Russian boxer and member of the State Duma Pyotr Valuev (1815–1890), Russian statesman and writer Vladimir Valuyev (born 1947), Russian naval officer
See also Valuev Circular, a secret decree which stopped all publications in Ukrainian language