Ammonium hexafluorogallate is an inorganic chemical compound with the chemical formula .

Synthesis A mechanochemical reaction between ammonium fluoride and gallium fluoride trihydrate (·) at a ratio of 3:1 produces the compound.

Also, a reaction of gallium(III) hydroxide, HF, and ammonium fluoride.

Physical properties Ammonium hexafluorogallate occurs in two polymorphic forms: tetragonal at low temperature and cubic at high temperature, with both transforming reversibly.

It has colorless crystals, which are soluble in water.

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