Holmium(III) iodide is an iodide of holmium, with the chemical formula of HoI3. It is used as a component of metal halide lamps.
Preparation
Holmium(III) iodide can be obtained by directly reacting holmium and iodine:
2 Ho + 3 I2 → 2 HoI3
Holmium(III) iodide can also be obtained via the direct reaction between holmium and mercury(II) iodide:
2 Ho + 3 HgI2 → 2 HoI3 + 3 Hg
The mercury produced in the reaction can be removed by distillation.
Holmium(III) iodide hydrate can be converted to the anhydrous form by dehydration with a large excess of ammonium iodide (since the compound is prone to hydrolysis).Georg Brauer (Hrsg.), unter Mitarbeit von Marianne Baudler u. a.: Handbuch der Präparativen Anorganischen Chemie. 3., umgearbeitete Auflage. Band I, Ferdinand Enke, Stuttgart 1975, ISBN 3-432-02328-6, S. 1077.
Properties
Holmium(III) iodide is a highly hygroscopic substance that dissolves in water. It forms yellow hexagonal crystals with a crystal structure similar to bismuth(III) iodide. In air, it quickly absorbs moisture and forms hydrates. The corresponding oxide iodide is also readily formed at elevated temperature.
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