Molybdic acid refers to hydrated forms of molybdenum trioxide and related species. The monohydrate (MoO3·H2O) and the dihydrate (MoO3·2H2O) are well characterized. They are yellow diamagnetic solids.
Structure of the solids
Solid forms of molybdic acid are coordination polymers. The monohydrate MoO3·H2O consists of layers of octahedrally coordinated MoO5·(H2O) units where 4 vertices are shared.Wells A.F. (1984) Structural Inorganic Chemistry 5th edition Oxford Science Publications The dihydrate (image shown above) has the same layer structure with the "extra" H2O molecule intercalated between the layers.
Structure of molybdic acid in solution In acidified aqueous solutions of molybdic acid, the complex is observed. Once again, molybdenum adopts octahedral molecular geometry, probably with three oxo ligands and three aquo ligands.Solution structure of molybdic acid from Raman spectroscopy and DFT analysis, Oyerindea O.F., Week C.L., Anbarb A.D., Spiro T.G. Inorganica Chimica Acta, 361, 4, (2008), 1000-1007,
The salts of molybdic acid are called molybdates. They arise by adding base to solutions of molybdic acid.
Applications Many molybdenum oxides are used as heterogeneous catalysts, e.g. for oxidations. Molybdic acid and its salts are used to make the Froehde reagent for the presumptive identification of alkaloids.
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