Bis(fulvalene)diiron is the organoiron complex with the formula (C5H4-C5H4)2Fe2. Structurally, the molecule consists of two ferrous centers sandwiched between fulvalene dianions. The compound is an orange solid with lower solubility in benzene than ferrocene. Its structure has been verified by X-ray crystallography. The compound has attracted some interest for its redox properties.
Preparation It was first prepared by Ullmann coupling of 1,1'-diiodoferrocene using copper but subsequent work produces the complex is 20-40% yield from dilithiofulvalene and ferrous chloride: 2(C5H4Li)2 + 2FeCl2 → (C5H4-C5H4)2Fe2 + 4LiCl
Related compounds Biferrocene
References