Molero is a surname. Notable people with the surname include:
Antonio Molero (born 1968), Spanish actor Armando Molero (1899/1900–1971), Venezuelan musician Diego Alfredo Molero Bellavia, Venezuelan politician Federico Molero Giménez (1908–1969), Spanish physicist and inventor Juan Molero (born 1968), Puerto Rican former baseball player Xiomara Molero (born 1971), Puerto Rican former volleyball player