Fluoride nitrates are mixed anion compounds that contain both fluoride ions and nitrate ions. Compounds are known for some amino acids and for some heavy elements. Some transition metal fluorido complexes that are nitrates are also known. There are also fluorido nitrato complex ions known in solution.
List nameformulamwcrystal systemspace groupunit cell ÅvolumedensitycommentreferenceL-ArgininiumL-Arg2+•F−•NO3−triclinicP1a=5.0130 b=10.6161 c=11.0352 α=87.471 β=86.038 γ=78.157 Z=22L-Arg2+•F−•3NO3−•HForthorhombicP212121a=7.3960 b=12.8672 c=26.990 Z=4L-histidineL-His2+•F−•NO3−(NH4)3SiF6NO3P63/mmc[Cr(NH3)5F](NO3)2hexakis(1H-imidazole)-cobalt(ii) fluoride nitrate tetrahydrate[Co(Im)6][F·NO3•(H2O)4]hexagonalP63/ma 8.972 c 21.077 Z=21469.31.402pink[Co(NH3)4(OH)F]NO3[Co(NH3)5F](NO3)2[Co(NH3)6]F(NO3)2[Co(en)2F2]NO3[As(ONO2)4]+[AsF6]−pale yellow; hydroscopic[Zr2F3OH(NO3)2(H2O)5]2+in solutionSnF2(ONO2)2SnF3(ONO2)stable < 40 °C; hydroscopicRb2SnF2NO3C2/mbirefringence 0.05 at 1064 nmSbF(ONO2)4SbF3(ONO2)2birefringence 0.098 at 546 nm(NH4)3SbF4(NO3)2orthorhombicPnmabirefringence 0.164 at 546 nm(NH4)3SbF3(NO3)3P21Rb2SbF3(NO3)2P21Xenon fluoride nitrateFXeONO2monoclinica = 4.6663 b = 8.799 c = 9.415 β = 90.325°386.63.648CsFHONO2[HfF4NO3]−in solution[HfF3(NO3)2]−in solutionHg3O2(NO3)ForthorhombicPnmaa=7.547 b=10.990 c=6.9906birefringence Δn = 0.23 @ 1064 nmHg16O12(NO3)6F2(H2O)orthorhombicIbcaa=11.6751 b=13.5050 c=20.727 Z=132687.783birefringence 0.17 at 546 nmPb2(NO3)2(H2O)F2Amm2birefringence 0.230 at 1064 nmPb3F5NO3triclinicPa 7.3796 b 12.147 c 16.8549, α 100.46° β 90.076° γ 95.517°layered; stable to 450 °CPb(OF)Cu3(SeO3)2(NO3)trigonalR3ma 6.6973 c 18.5548 Z=3720.755.175yellow; stable to 400 °CPbCdF(SeO3)(NO3)orthorhombicPca21a=11.121 b=10.366 c=5.3950NLO 2.6×KDP; band gap 4.42 eVBaPb2F5NO3Bi2OF3(NO3)hexagonalP63/mband gap 3.5 eVBi6O6F5(NO3)trigonalR3band gap 4.0 eV[(UO2)4F13][Sr3(H2O)8](NO3)·H2O1814.13triclinicPa = 10.793, b = 10.918, c = 13.231 α = 92.570°, β = 109.147°, γ = 92.778° Z = 2.1468.14.105yellow
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