Olayiwola is a Nigerian surname. Notable people with the surname include:
Lamidi Olayiwola Adeyemi III (born 1938), traditional ruler of Oyo Jacqueline Nwando Olayiwola, American physician, author, and professor Porsha Olayiwola, American poet Oluwole Olayiwola Amusan, Nigerian academic Olayiwola Oluwatobiloba Victor, Nigerian online streamer and YouTuber