Anti-structure

In crystallography, an anti-structure is obtained from a salt structure by exchanging anion and cation positions.

For instance, calcium fluoride, CaF2, crystallizes in a cubic motif called the fluorite structure. The same crystal structure is found in numerous ionic compounds with formula AB2, such as ceria (CeO2), zirconia (cubic ZrO2), uranium dioxide (UO2). In the corresponding anti-structure, called the antifluorite structure, anions and cations are swapped, such as beryllium carbide (Be2C) or lithium oxide (Li2O), potassium sulfate (K2SO4).

Other anti-structures include:Peter Paetzold: Chemie. Eine Einführung. de Gruyter, Berlin 2009 anti-SnO2: Ti2N anti-PbCl2: Co2P anti-CdCl2: Co2N anti-CdI2: Cs2O anti-NbS2: Hf2S anti-ReO3: Cu3N anti-LaF3: Cu3P, Cu3As

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