Volek (Czech feminine: Volková) is a surname. Notable people with the surname include:
Billy Volek (born 1976), American football player David Volek (born 1966), Czech ice hockey player Jaroslav Volek (1923–1989), Czech musicologist Zdeněk Volek (born 1985), Czech footballer
Fictional characters Nika Volek, a minor character on the American television series Prison Break
See also