The Santos Basin () is an approximately large mostly offshore sedimentary basin. It is located in the south Atlantic Ocean, some southeast of Santos, Brazil. The basin is one of the Brazilian basins to have resulted from the break-up of Gondwana since the Early Cretaceous, where a sequence of rift basins formed on both sides of the South Atlantic; the Pelotas, Santos, Campos and Espírito Santo Basins in Brazil, and the Namibia, Kwanza and Congo Basins in southwestern Africa.

Santos Basin is separated from the Campos Basin to the north by the Cabo Frio High and the Pelotas Basin in the south by the Florianópolis High and the northwestern boundary onshore is formed by the Serra Do Mar coastal range. The basin is known for its thick layers of salt that have formed structures in the subsurface due to halokinesis. The basin started forming in the Early Cretaceous on top of the Congo Craton as a rift basin. The rift stage of the basin evolution combined with the arid Aptian climate of the southern latitudes resulted in the deposition of evaporites in the Late Aptian, approximately 112 million years ago. The phase of rifting was followed by a thermal sag phase and drift stage in the widening of the South Atlantic Ocean. This process led to the deposition of a more than thick succession of clastic and carbonate sediments.

One of the largest Brazilian sedimentary basins, it is the site of several recently (2007 and later) discovered giant oil and gas fields, including the first large pre-salt discovery Tupi (8 billion barrels), Júpiter (1.6 billion barrels and 17 tcf of gas), and Libra, with an estimated 8 to 12 billion barrels of recoverable oil. Main source rocks are the lacustrine shales and carbonates of the pre-salt Guaratiba Group and the marine shales of the post-salt Itajaí-Açu Formation. Reservoir rocks are formed by the pre-salt Guaratiba sandstones, limestones and microbialites, the Albian limestones of the Guarujá Formation and the Late Cretaceous to Paleogene turbiditic sandstones of the Itanhaém, Juréia, Itajaí-Açu, Florianópolis and Marambaia Formations. The mobile salt of the Ariri Formation forms regional seals, as well as the shales of the post-salt sedimentary infill. In 2014, the total production of only the sub-salt reservoirs accumulated to more than . In 2017, the Santos Basin accounted for 35% of Brazil's oil, with the northern neighbour Campos Basin at 55%.

Etymology The Santos Basin is named after the coastal city of Santos in the state of São Paulo.

Description

The Santos Basin is a mostly offshore sedimentary basin across the Tropic of Capricorn, bordering from north to south the Brazilian states of Rio de Janeiro, Sáo Paulo, Paraná and Santa Catarina.Constantino et el., 2016, p.200 The basin covers an area of approximately ,Clemente, 2013, p.18 and is bounded in the north by the Cabo Frio High, separating the basin from the Campos Basin and the Florianópolis High and Fracture Zone, separating the Santos Basin from the Pelotas Basin.Contreras, 2011, p.1

Along the Brazilian coast, the basin is bounded by the Serra do Mar and stretches from Cabo Frio in the northeast to Florianópolis in the southwest. The city of Rio de Janeiro is located at the coastal edge of the Santos Basin in the northern portion, Santos, Guarujá and the islands of Ilhabela in the central area and Itajaí and Balneário Camboriú in the south of the basin. Within the basin, several highs are located. The Outer High, in the distal part of the Santos Basin, is the most prominent and extensive intra-basinal high with an approximate area of . The Outer High is likely a segmented series of rift fault-block shoulders which were uplifted and eroded during the Late Barremian.Gomes et al., 2009, p.3

The climate of the onshore stretch of the basin ranges from tropical savanna climate (Aw), tropical monsoon climate (Am) and tropical rainforest climate (Af) to a humid subtropical climate (Cfa). The onshore portion of the Santos Basin is in the Serra do Mar coastal forests ecoregion of the Atlantic Forest biome. On the islands of the Superagüi National Park in the Santos Basin, the endemic critically endangered Superagüi lion tamarin (Leontopithecus caissara) has its restricted habitat.

Tectonic history

The South Atlantic margin developed on Archean stable cratons consisting of hard and resistant rocks and partly on the Neoproterozoic mobile belts composed of less resistant metamorphic rocks.Clemente, 2013, p.3 The Precambrian basement of the Santos Basin is exposed as the Araçuaí Belt along the Brazilian coast, most notably in the inselbergs of Rio de Janeiro, of which Sugarloaf Mountain is the most iconic. The ancient rocks consist of a Neoproterozoic to Cambrian high-grade metamorphic core of granites and gneisses, formed during the collision of Gondwana in the Pan-African-Brasiliano orogeny.Owen, 2014, p.36 Basalts similar to the Paraná and Etendeka traps, exposed to the west in the Paraná Basin, have been found underlying the Santos Basin.Peate, 1997, p.220 The Tristan da Cunha hotspot, known as the Tristan hotspot, is considered the driver behind the formation of these flood basalts.Beasley et al., 2010, p.31

During the Early Cretaceous, the former continent Gondwana, as southern part of Pangea, starting to break-up, resulting in a sequence of rift basins bordering the present-day South Atlantic. The Pelotas-Namibia spreading commenced in the Hauterivian, around 133 million years ago and reached the Santos Basin to the north in the Barremian. Seafloor spreading continued northwards to the Campos Basin in the Early Albian, at approximately 112 Ma.

Five tectonic stages have been identified in the Brazilian basins:Contreras, 2011, p.7 Pre-rift stage – Jurassic to Valanginian Syn-rift stage – Hauterivian to Late Barremian Sag stage – Late Barremian to Late Aptian Post-rift stage – Early to Middle Albian Drift stage – Late Albian to Holocene

The sag phase in the Santos Basin was characterised by thermal subsidence and generated restricted depocentres with relatively uniform water depths, ranging from . The Late Aptian climate was arid with high evaporation rates which triggered hypersaline conditions in these marginal sag basins. This resulted in the accumulation of thick layers of evaporites along the Brazilian and southwestern African continental margins, a process continuing towards the north later in the Cretaceous.Contreras, 2011, p.8 The deposition of the lowermost of salt in the Aptian would have taken approximately 20,000 to 30,000 years.Bryant et al., 2012, p.51 With the continental break-up of the Santos and Campos Basins from the opposite Namibia and Kwanza Basins, oceanic circulation returned during the post-rift stage. The drift phase since the Late Cretaceous produced a thick sequence of clastic and carbonate deposits. Differential thermal regimes and sediment loading of these units produced halokinesis; salt movement in the subsurface. The resulting salt diapirs, listric and thrust faults and various salt-related structures produced several stratigraphic and combined stratigraphic-structural traps for hydrocarbon accumulation in the Brazilian and southwest African offshore.

During the phases of halokinesis, dated to the Albian to Paleocene, several areas of the now deep water distal part of the Santos Basin were exposed to subaerial conditions and suffered erosion. The distal parts of the basin were affected by E-W to NW-SE oriented shortening, sub-perpendicular to the Brazilian margin.Alves et al, 2017, p.319

Stratigraphy

The basement of the Santos Basin is composed of granites and gneisses of the Araçuarí Belt that formed at the western boundary of the Congo Craton. The erosion resistant metamorphic and magmatic rocks are exposed in the Serra do Mar, forming the edge of the Santos Basin along the Brazilian coast.

The total stratigraphic thickness of the sediments in the Santos Basin has been estimated at and has been described in detail by Clemente in 2013.Clemente, 2013, p.20

I – Guaratiba Group (Hauterivian-Aptian, pre-salt sequence)

The Guaratiba Group is thick and includes four formations, from old to young the Camboriú, Piçarras, Itapema and Barra Velha Formations. The group is equivalent to the Lagoa Feia Group of the Campos Basin.

Camboriú Formation The Camboriú Formation is thick and includes the basaltic rocks with a basin–wide distribution. The basalts are dark green to dark grey, holocrystalline, medium grained, with an ophiolitic texture. The main components are plagioclase and augite, usually fresh, non-altered.

Piçarras Formation The Piçarras Formation is thick and consists of clastic and carbonate rocks. The formation includes reddish polymictic conglomerates, with clasts of basalt and quartz in a clay-sandy matrix. It also includes white, reddish lacustrine coquinas (shelly limestones) and sandstones, siltstones and shales of stevensite composition. Its age, based on the ostracod assemblages, is Hauterivian to Aptian.

The conglomerates and sandstones of the formation are representative of an alluvial environment. The coquinas represent a shallow lacustrine environment. Similar to the Atafona Formation of the Campos Basin, the sandstones, stevensite-bearing siltstones and shales represent an alkaline lacustrine environment affected by volcanic activity. The shales represent deeper lacustrine waters in more distal areas. The alternation of the two facies implies a series of alluvial progradation-retractions into the Cretaceous carbonate lakes. The low textural and compositional maturity of conglomerates and sandstones implies the basin was supplied from areas close to the basin margins.Clemente, 2013, p.21

Itapema Formation The Itapema Formation is several hundreds of metres thick and consists of calcirudites (limestones) and dark shales. The calcirudite limestones consist of fragmented bivalve shells, frequently dolomitized and silicified. In more distal sections, the formation consists of dark organic matter rich shales. In the well 1-RSJ-625, the formation includes of radioactive shales interbedded with carbonates. These facies are thought to represent a lacustrine environment. The organic matter-rich shales are one of the main source rocks of the Santos Basin. This formation is correlative with the Coqueiros Formation in the Campos Basin. The age of the Itapema Formation is Barremian to Aptian.

Barra Velha Formation The Barra Velha Formation is approximately thick. In the proximal sections, the formation comprises limestones of stromatolites and laminated microbialites. In the distal sections, it is composed of shales. Interbedded with the laminated microbialites there are limestones with packstone and grainstone textures made up of algal clasts and bioclasts (fragmented ostracods). The carbonates frequently are partly or completely dolomitized. These facies represent a transitional continental and shallow marine environment. The age of this formation has been estimated to be Late Barremian to Aptian. It is correlative with the Macabu Formation in the Campos Basin, as both are typified by laminated microbialites and stromatolites. These limestones are one of the sub-salt reservoirs in the Santos Basin.

II – Ariri Formation (Late Aptian, salt sequence)

The Ariri Formation is in the thick and may be up to thick in other areas of the basin. It is predominantly composed of evaporites. The formation is characterized by thick intervals of white halite, associated with white anhydrite, ochre greyish calcilutites, shales and marls. The sedimentary environment probably was restricted marine including mudflat sabkhas, evolving under an arid climate. The ostracod assemblages of this formation indicate a neo-Algoas age (local time scale).

III – Camburi Group (Albian-Cenomanian, lower post-salt sequence) The Camburi Group is up to thick and includes three formations, Florianópolis, Guarujá and Itanhaém.Clemente, 2013, p.22