Valdivieso is a Spanish-language surname derived from the Valdivielso valley in Burgos, Spain. Notable people with the surname include:
Alfonso Valdivieso (born 1949), Colombian lawyer and politician Antonio de Valdivieso (1495–1549), Spanish Roman Catholic prelate who served as Bishop of Nicaragua Domingo Valdivieso (1832–1872), Spanish painter Edison Valdivieso (born 1989), Ecuadorian footballer Enrique Valdivieso (1943–2025), Spanish art historian Francisco Valdivieso y Prada (1773–1828), Peruvian lawyer, magistrate and politician Gabriel Larraín Valdivieso (1925–2008), Chilean Roman Catholic bishop Guillermo Vivas Valdivieso (1881–1965), Puerto Rican journalist and politician José Valdivieso (1921–1996), Argentinian footballer and manager Juan Valdivieso (1910–2007), Peruvian footballer and manager Juan Pablo Valdivieso (born 1981), American-born Peruvian swimmer Luis Valdivieso Montano (born 1951), Peruvian economist and diplomat Luis P. Valdivieso (ca.1845–ca.1920), Puerto Rican politician Luz Valdivieso (born 1977), Chilean actress Mercedes Valdivieso (1924–1993), Chilean writer Pamela Valdivieso, Salvadorean beauty pageant winner Pedro Valdivieso (1922–?), Peruvian footballer and manager Rafael Valentín Valdivieso (1804–1878), Chilean priest and lawyer Ramón Valdivieso (1902–1996), Chilean medical doctor and politician Yesmín M. Valdivieso (born 1961), Puerto Rican politician, Comptroller of Puerto Rico