Ball clays are kaolinitic sedimentary clays that commonly consist of 20–80% kaolinite, 10–25% mica and 6–65% quartz, along with small amounts of organic matter (such as lignite) and trace amounts of other minerals such as pyrite and siderite.
They are a common raw material for various types of ceramics, where their primary roles are to impart unfired strength, plasticity or to aid rheological stability during the shaping processes.'Ceramic Raw Materials' 2nd edition. W.E. Worrall. Pergamon Press, 1982 Most ball clays impart colours ranging from buff to cream to off-white when fired in an oxidising atmosphere.'Industrial Minerals & Rocks – Commodities, Markets And Uses' J. E. Kogel. Society For Mining, Metallurgy And Exploration, 2006
The name "ball clay" is derived from the form of the extracted material when dug by spade as cubes, which then became rounded during subsequent transport, in Dorset and Devon, England during the early days of the industry during the 18th century.'Ball Clay Basics' P. S. Powell. Ceram. Eng. Sci. Proc., 16 200–206, 1995. Pg. 200
In 2008, UK production of ball clay was reported to be worth £82 million, with sanitaryware manufacturers being the largest single group of end users, representing 40% by volume.'Ball Clay' Mineral Planning Factsheet. British Geological Survey. 2008. Locations
Deposits are relatively scarce due to the combination of geological factors needed for their formation and preservation. Commercial extraction of ball clays is undertaken across the world, including:'The Constitution, Evaluation And Ceramic Properties Of Ball Clays' I. R. Wilson. Cerâmica vol.44 no.287-288 São Paulo May/June/July/Aug. 1998 Argentina (San Julian area of Patagonia) Brazil (various locations including the region around São Paulo – São Simão, Suzano and Ribeirão Pire) China (various including Guangdong Province) Czech Republic (Cheb, Plzeň, Prague, Most, S. Bohemia and W. Moravia) Germany (various locations but the main is the Westerwald region) Indonesia (various locations including the island of Kalimantan) Thailand (Lampang) United Kingdom (the Bovey Basin of south Devon, the Petrockstow Basin in north Devon and the area around Wareham in south-east Dorset) USA (Kentucky, Tennessee and Texas)
Production output Global production of ball clay by country for 2002–2003 was estimated to be: Country1,000 tonnesSouth Africa10Africa – total10China2,000Malaysia600Indonesia500Thailand300Vietnam200India150Asia – total3,750Ukraine3,500Germany3,000Spain1,200United Kingdom1,000Turkey550Czech Republic400France400Italy100Poland50Europe – total10,200United States1,200North America – total1,200Australia80Oceania – total80Brazil250Argentia50Chile5South America – total350Global – total15,385
Typical properties Some selected typical properties of various UK ball clays are:
Product name Hycast Rapide Sanblend 75 Slurry Prestige BLU Prestige TA Hyplas 71 Hymod Excelsior Hymod Blue Source Bovey Bovey Bovey Petrockstow Petrockstow Wareham Warehan Producing company Imerys WBB WBB WBB Imerys Imerys Imerys Residue, wt% <125 μm 2.0 0.1 0.2 0.5 1.0 0.3 0.1 % <2 μm 70 78 82 77 57 92 89 % <1 μm 60 65 - - 50 87 79 % <0.5 μm 45 - - - 40 80 65 SiO2, % 55.0 53.7 54.0 60.5 69.0 49.0 53.0 Al2O3, % 29.0 28.9 31.2 25.8 20.0 35.0 31.0 Fe2O3, % 1.1 1.2 1.0 1.9 0.9 1.6 1.4 TiO2, % 1.1 1.1 1.2 1.5 1.7 1.3 1.0 CaO, % 0.2 - - - 0.1 0.3 0.3 MgO, % 0.3 - - - 0.4 0.3 0.5 K2O, % 1.6 2.5 3.0 2.9 1.9 1.2 3.2 Na2O, % 0.2 - - - 0.4 0.2 0.4 Carbon, % 2.0 2.5 0.2 0.6 0.1 0.3 0.4 LOI, % 12.0 12.0 9.0 8.0 5.4 12.0 9.2
History in the UK The ceramic use of ball clays in Britain dates back to at least the Roman era. More recent trade began when a clay was needed to make tobacco pipes in the 16th and 17th century. In 1771 Josiah Wedgwood signed a contract for 1,400 tons a year of ball clay with Thomas Hyde of Purbeck, enabling the production of thinner-walled ceramics.
See also
Purbeck Ball Clay
References